Silicon carbide (SiC) is a ceramic compound
of silicon and carbon.
The word moissanite is a trade name
given to silicon carbide for use in
the gem business.
Most silicon carbide is man-made for use as an abrasive
(when it is often known by the trademark carborundum),
or more recently as a semiconductor and moissanite gemstones.
The simplest manufacturing process is to combine silica
sand and carbon at a high temperature, between 1600°C
and 2500°C.
The material formed in the Acheson furnace varies in
purity, according to its distance from the graphite
resistor that is the heat source. Clear, pale yellow
and green crystals have the highest purity, and are
found closest to the resistor. The colour changes to
blue and black at greater distance from the resistor,
and these darker crystals are less pure, and usually
doped with aluminium, which decreases electrical conductivity.
Purer silicon carbide can be made by the more expensive
process of chemica vapor deposition. Commercial large
single crystal silicon carbide is grown using a physical
vapor transport commonly known as modified Lely method.
Discovery
The material was discovered by Edward Goodrich Acheson
in 1893 or 1893, and he not only developed the electric
batch furnace by which SiC is still made today, but
also formed The Carborundum Company to manufacture it
in bulk, initially for use as an abrasive. It is said
that Acheson was trying to dissolve carbon in molten
corundum (alumina) and discovered the presence of hard,
blue-black crystals which he believed to be a compound
of carbon and corundum: hence carborundum. Or, he named
the material carborundum by analogy to corundum, which
is another very hard substance (9 on the Mohs
scale).
Properties
Alpha silicon carbide (a-SiC) is most common, and is
formed at temperatures >2000°C. Alpha SiC has
the typical hexagonaln crystal structure. Beta modification
(ß-SiC), with a face-centered
cubic crystal structure, is formed at temperatures of
below 2000°C, but has relatively few commercial
uses. Silicon carbide has a specific gravity of 3.2,
and its high melting point (approximately 2700 °C)
makes silicon carbide useful for bearings and furnace
parts. It is also highly inert chemically. There is
currently much interest in its use as a semiconductor
material in electronics, where its high thermal conductivity,
high electric field breakdown strength and high maximum
current density make it more promising than silicon
for high-powered devices. In addition, it has strong
coupling to microwave radiation and that, together with
its high melting point permits practical use in heating
and casting metals. SiC also has very low thermal expansion
coefficient and no phase transitions that would cause
discontinuities in thermal expansion.
Pure SiC is clear. The brown to black color of industrial
product is caused by iron impurities. The rainbowish
lustre of the crystals is caused by the passivation
layer of silicon dioxide that forms on its surface.
As a gemstone, silicon carbide is similar to diamond
in several important ways: it is transparent and extremely
hard (9.25 on the Mohs scale, compared to 10 for diamond),
with an index of refraction between 2.65 and 2.69 (compared
to 2.42 for diamond). SiC has a hexagonal crystalline
structure.
Found
in nature
Naturally occurring moissanite is extremely rare, as
it is not formed naturally in any quantity within the
Earth, and thus is found only in tiny quantities in
certain types of meteorite and as microscopic traces
in corundum deposits and kimberlite. Virtually all of
the silicon carbide sold in the world, including moissanite
gemstones, is synthetic. Natural moissanite was first
found in 1905 as a small component of a meteorite in
Arizona by Dr. Ferdinand Henri Moissan, after whom the
material is named in the gem market. Moissan's discovery
of naturally occurring SiC was disputed at first because
his sample may have been contaminated by silicon carbide
saw blades that were already on the market at that time.
Uses
Semiconductor
Structural material
Astronomy
Silicon carbide's hardness and rigidity make it a desirable
mirror material for astronomical work, although they
also make manufacturing and figuring such mirrors quite
difficult.
Silicon carbide may be a major component of the mantles
of as-yet hypothetical carbon planets.
Grit
Disc brake
Diesel Particulate Filter
Cutting Tools
Heating Element
As a gemstone
In 1998 C3, Inc. (Charles and Colvard) [Nasdaq: CTHR],
a subsidiary of Cree Research, Inc., introduced gem-quality
synthetic silicon carbide
onto the market under the name "moissanite"
,marketing it as a lower-cost alternative to diamond.
For example, a 1 carat moissanite gem sells for about
$600 (2005 USD), while a diamond of similar size and
color typically runs for upwards of $4500. Synthetic
moissonite is approximately as hard as diamond, with
a slightly higher index of refraction and greater dispersion;
these qualities make SiC a decent and durable diamond
simulant. It is interesting to note that the higher
dispersion and index of refraction means moissanite
has more fire and brilliance than diamond.
While some properties of moissanite are closer to diamond
than those of cubic
zirconia, another synthetic diamond simulant, once
its properties are known moissanite is perhaps even
easier to identify. Jewellers were at first fooled by
moissanite's thermal conductivity which approximates
that of diamond, rendering older thermal testers useless;
what worked with cubic zirconia did not work with moissanite.
Moissanite is harder than cubic zirconia (9 1/4 vs.
8 1/2), lighter (SG 3.33 vs. 5.6), and much more resistant
to heat. This results in a stone of higher lustre, sharper
facets and good resilience: loose moissanites may be
placed directly into ring moulds, the stones remain
undamaged from temperatures up to twice the 900°C
melting point of 18k gold.
In
popular culture
In 2001: A Space Odyssey and the related
series of books and movies (by Arthur C. Clarke and
Stanley Kubrick, among others) the monoliths (or at
least their exteriors) were made of silicon carbide. |