Diamond is one of the two best known forms (or allotropes) of carbon, whose hardness and high dispersion of light make it useful for industrial applications and jewelry (the other equally well known allotrope is graphite). Diamonds are specifically renowned as a mineral with superlative physical qualities - they make excellent abrasives because they can only be scratched by other diamonds, which also means they hold a polish extremely well and retain luster. About 130 million carats (26,000 kg) are mined annually, with a total value of nearly USD $9 billion.
The name "diamond" derives from the ancient Greek adamas (ad?µa?; "invincible"). They have been treasured as gems since their use as religious icons in India at least 2,500 years ago—and usage in drill bits and engraving tools also dates to early human history. Popularity of diamonds has risen since the 19th century because of improved cutting and polishing techniques, and they are commonly judged by the "four Cs": carat, clarity, color, and cut. Although nearly four times the mass of natural diamonds are produced as synthetic diamond each year, the vast majority of synthetic diamond production remains small, imperfect diamonds suitable only for industrial-grade use, with gem-quality synthetic diamonds only recently becoming available.
Most natural diamonds originate from central and southern Africa , although significant sources of the mineral have been discovered in Canada, Russia, Brazil, and Australia. They are generally mined from volcanic pipes, which are deep in the Earth where the high pressure and temperature enables the formation of the crystals. The mining and distribution of natural diamonds are subjects of frequent controversy—such as with concerns over the sale of conflict diamonds by African paramilitary groups.

Crystal structure

Diamonds typically crystallize in the face-centered cubic crystal system and consist of tetrahedrally bonded carbon atoms. The unit cell of diamond has a two atom basis at (0,0,0) and (1/4,1/4,1/4), which means half of the atoms are at lattice points and the other half are offset by (1/4,1/4,1/4), where 1 is the length of a side of the unit cell.
The tetrahedral arrangement of atoms in a diamond crystal is the source of many of diamond's properties. Graphite, another allotrope of carbon, has a rhombohedral crystal structure and as a result shows dramatically different physical characteristics — contrary to diamond, graphite is a very soft, dark gray, opaque mineral. Other elements of the carbon group such as silicon have forms analogous to diamond.
Lonsdaleite is a polymorph of diamond (and a distinct mineral species) that crystallizes with hexagonal symmetry; it is rarely found in nature, but is characteristic of synthetic diamonds. A crypto crystalline variety of diamond is called carbonado. A colorless, gray or black diamond with a tiny radial structure is a spherulite.

Electromagnetic properties

Optical properties
Diamonds exhibit a high dispersion of visible light. This strong ability to split white light into its component colors is an important aspect of diamond's attraction as a gemstone, giving it impressive prismatic action that results in so-called fire in a well-cut stone. The luster of a diamond, a characterization of how light interacts with the surface of a crystal, is brilliant and is described as adamantine, which simply means diamond-like. This is owed to their high refractive index of 2.417 (at 589.3 nm), which causes total internal reflection to occur. Some diamonds exhibit fluorescence of various colors (predominately blue) under long wave ultraviolet light. Nearly all diamonds fluoresce bluish-white, yellow or green under X-rays and this property is used extensively in mining to separate the fluorescing diamond from the non-fluorescing rock. Most diamonds show no fluorescence although colored diamonds show a wider range of fluorescence than the blue fluorescence normally observed in clear diamonds

Except for most blue diamonds, which are semiconductors, diamonds are good electrical insulators. Blue diamonds owe their semi conductive property to boron impurities, which act as a doping agent and cause p-type semiconductor behavior. Blue diamonds which are not boron-doped, such as those recently recovered from the Argyle diamond mine in Australia that owe their color to an overabundance of hydrogen atoms, are not semiconductors.

Thermal properties

Unlike most electrical insulators, diamond is a good conductor of heat because of the strong covalent bonding within the crystal. Most natural blue diamonds contain boron atoms which replace carbon atoms in the crystal matrix, and also have high thermal conductivity. Specially purified synthetic diamond has the highest thermal conductivity (2000–2500 W/(m•K), five times more than copper) of any known solid at room temperature. Because diamond has such high thermal conductance it is already used in semiconductor manufacture to prevent silicon and other semi conducting materials from overheating.

Diamond cutting is the art and science of creating a gem-quality diamond out of mined rough. The cut of a diamond describes the manner in which a diamond has been shaped and polished from its beginning form as a rough stone to its final gem proportions. The cut of a diamond describes the quality of workmanship and the angles to which a diamond is cut. Often diamond cut is confused with "shape."
There are mathematical guidelines for the angles and length ratios at which the diamond is supposed to cut at in order to reflect the maximum amount of light. Round brilliant diamonds, the most common, are guided by these specific guidelines, though fancy cut stones are not able to be as accurately guided by mathematical specifics.
The techniques for cutting diamonds have been developed over hundreds of years, with perhaps the greatest achievements made in 1919 by mathematician and gem enthusiast Marcel Tolkowsky. He developed the round brilliant cut by calculating the ideal shape to return and scatter light when a diamond is viewed from above. The modern round brilliant has 57 facets (polished faces), counting 33 on the crown (the top half), and 24 on the pavilion (the lower half). The girdle is the thin unpolished middle. The function of the crown is to diffuse light into various colors and the pavilion's function to reflect light back through the top of the diamond.
Tolkowsky defines the ideal dimensions to have:

• Table percentage (table diameter divided by overall diameter) = 53%
• Depth percentage (Overall depth divided by the overall diameter) = 59.3%
• Pavilion Angle (Angle between the girdle and the pavilion) = 40.75°
• Crown Angle (Angle between the girdle and the crown) = 34.5°
• Pavilion Depth (Depth of pavilion divided by overall diameter) = 43.1%
• Crown Depth (Depth of crown divided by crown diameter) = 16.2%

The culet is the tiny point at the bottom of the diamond. This should be a negligible diameter, otherwise light leaks out of the bottom. Tolkowsky's ideal dimensions did not include a girdle. However, a thin girdle is required in reality in order to prevent the diamond from easily chipping in the setting. A normal girdle should be about 1%–2% of the overall diameter.
The further the diamond's characteristics are from Tolkowsky's ideal, the less light will be reflected. However, there is a small range in which the diamond can be considered "ideal." Today, because of the relative importance of carat weight in society, many diamonds are often intentionally cut poorly to increase carat weight. There is a financial premium for a diamond that weighs the magical 1.0 carat, so often the girdle is made thicker or the depth is increased. Neither of the these tactics make the diamond appear any bigger, but it also greatly reduces the sparkle of the diamond. So a poorly cut 1.0 carat diamond may have the same diameter and appear as large as a 0.85 carat diamond. The depth percentage is the overall quickest indication of the quality of the cut of a round brilliant. "Ideal" round brilliant diamonds should not have a depth percentage greater than 62.5%. Another quick indication is the overall diameter. Typically a round brilliant 1.0 carat diamond should have a diameter of about 6.5 mm. Mathematically, the diameter in millimeters of a round brilliant should approximately equal 6.5 times the cube root of carat weight, or 11.1 times the cube root of gram weight.

The quality of a diamond's cut is widely considered the most important of the four Cs in determining the beauty of a diamond; indeed, it is commonly acknowledged that a well-cut diamond can appear to be of greater carat weight, and have clarity and color appear to be of better grade than they actually are. The skill with which a diamond is cut determines its ability to reflect and refract light.
In addition to carrying the most importance to a diamond's quality as a gemstone, the cut is also the most difficult to quantitatively judge. A number of factors, including proportion,symmetry, and the relative angles of various facets, are determined by the quality of the cut and can affect the performance of a diamond. A poorly cut diamond with facets cut only a few degrees out of alignment can result in a poorly performing stone. For a round brilliant cut, there is a balance between "brilliance" and "fire." When a diamond is cut for too much "fire," it looks like a cubic zirconia, which gives off much more "fire" than real diamond. A well executed round brilliant cut should reflect most light out from the tabletop and make the diamond appear white when viewed from the top. An inferior cut will produce a stone that appears dark at the center and in some extreme cases the ring settings may show through the top of the diamond as shadows.
Several different theories on the "ideal" proportions of a diamond have been and continue to be advocated by professional gemologists. Recently, there has been a shift away from grading cut by the use of various angles and proportions toward measuring the performance of a cut stone. A number of specially modified viewers and machines have been developed toward this end. They included the FireScope, a.k.a. SymmetriScope or IdealScope (tests for light leakage, light return and proportions), Hearts and Arrows Viewer (test for " heards and arrows" characteristic pattern observable on stones exhibiting high symmetry), GemEx BrillianceScope (tests for direct light performance results of a diamond), Isee2 Machine (tests for diffused light performance results of a diamond), and ASET (test for AGS cut grade). These viewers and machines often help consumers determine the light performance results of the diamond in addition the traditional 4 C's. Along with this shift there are a few companies that provide results on these viewers and machines in addition to the original 4c's. Solasfera Diamond has results of Hearts and Arrows viewer, GemEx BrillianceScope, and FireScope. Hearts on Fire Diamond has results of the Hearts and Arrows viewer. EightStar Diamond has results of the FireScope

The cutting process

The process of shaping a rough diamond into a polished gemstone is both an art and a science. The choice of cut is often decided by the original shape of the rough stone, location of the inclusions and flaws to be eliminated, the preservation of the weight, popularity of certain shapes amongst consumers and many other considerations. The round brilliant cut is preferred when the crystal is an octahedron, as often two stones may be cut from one such crystal. Oddly shaped crystals such as macles are more likely to be cut in a fancy cut—that is, a cut other than the round brilliant—which the particular crystal shape lends itself to.
Even with modern techniques, the cutting and polishing of a diamond crystal always results in a dramatic loss of weight; rarely is it less than 50%. Sometimes the cutters compromise and accept lesser proportions and symmetry in order to avoid inclusions or to preserve the carat rating. Since the per carat price of diamond shifts around key milestones (such as 1.00 carat), many one-carat diamonds are the result of compromising "Cut" for "Carat." Some jewelry experts advise consumers to buy a 0.99 carat diamond for its better price or buy a 1.10 carat diamond for its better cut, avoiding a 1.00 carat diamond which is more likely to be a poorly cut stone.

Diamonds are thought to have been first recognized and mined in India, where significant alluvial deposits of the stone could then be found. The earliest written reference can be found in the Sanskrit text Arthasastra, which was completed around 296 BCE, describes diamond's hardness, luster, and dispersion. Diamonds quickly became associated with divinity, being used to decorate religious icons, and were believed to bring good fortune to those who carried them. Ownership was restricted among various castes by color, with only kings being allowed to own all colors of diamond.
In February 2005, a joint Chinese-U.S. team of archaeologists reported the discovery of four corundum -rich stone ceremonial burial axes originating from China's Liangzhu and Sanxingcun cultures (4000 BCE–2500 BCE) which, because of the axes' specular surfaces, the scientists believe were polished using diamond powder . Although there are diamond deposits now known to exist close to the burial sites, no direct evidence of coeval diamond mining has been found: the researchers came to this conclusion by polishing corundum using various lapidary abrasives and modern techniques then comparing the results using an atomic force microscope. At that scale, the surface of the modern diamond-polished corundum closely resembled that of the axes; however, the polishes of the latter were superior.
Diamonds were traded to both the east and west of India and were recognized by various cultures for their gemological or industrial uses. The Roman writer Pliny the Elder noted diamond's ornamental uses, as well as its usefulness to engravers because of its hardness, in his work Naturalis Historia. In China, diamonds seem to have been used primarily for engraving jade and drilling holes in beads. Archeological evidence from Yemen suggests that diamonds were used as drill tips as early as the 4th century BCE. In Europe, however, diamonds disappeared for almost 1,000 years following the rise of Christianity because of two effects: early Christians rejected diamonds because of their earlier use in amulets, and Arabic traders restricted the flow of trade between Europe and India.

Diagram of old diamond cuts showing the evolution from the most primitive (point cut) to the most advanced pre-Tolkowsky cut (old European).

Until the late Middle Ages, diamonds were most prized in their natural octahedral state, perhaps with the crystal surfaces polished to increase luster and remove foreign material. Around 1300, the flow of diamonds into Europe increased via Venice’s trade network, with most flowing through the low country ports of Bruges, Antwerp, and Amsterdam. During this time, the taboo against cutting diamonds into gem shapes, which was established over 1,000 years earlier in the traditions of India, ended allowing the development of diamond cutting technology to begin in earnest. By 1375, a guild of diamond polishers had been established at Nuremberg. Over the following centuries, various diamond cuts were introduced which increasingly demonstrated the fire and brilliance that makes diamonds treasured today: the table cut, the briolette (around 1476), the rose cut (mid-16th century), and by the mid-17th century, the Mazarin, the first brilliant cut diamond design. In 1919, Marcel Tolkowsky developed an ideal round brilliant cut design that has set the standard for comparison of modern gems; however, diamond cuts have continued to be refined.
The rise in popularity of diamonds as gems seems to have paralleled increasing availability through European history. In the 13th century, King Louis IX of France established a law that only the king could own diamonds. However, within a century diamonds were popular gems among the moneyed aristocratic and merchant classes, and by at latest 1477 had begun to be used in wedding rings. Popularity continued to rise as new cuts were developed that enhanced the diamond's aesthetic appeal, and has largely continued unabated to this day; diamonds have proven popular with all classes in society as their cost has become within reach. A number of large diamonds have become historically significant objects, as their inclusion in various sets of crown jewels and the purchase, sale, and sometimes theft of notable diamonds, have sometimes become politicized.

Record-holding diamonds

The Cullinan Diamond, owned by Queen Elizabeth II was the largest gem-quality rough diamond ever found (1905), at 3,106.75 carats. One of the diamonds cut from it, Cullinan I or the Great Star of Africa, was formerly the largest cut diamond at 530.2 carats, but now that title has been taken by the Golden Jubilee (1985), a 545.67 carat yellow-brown diamond. The largest flawless and colorless (grade D) diamond is the Centenary Diamond which weighs 273.85 carats. The Millennium Star is the second largest (1990) at 203.04 carats.

A number of large or extraordinarily colored diamonds have gained fame, both as exquisite examples of the beautiful nature of diamonds, and because of the famous people who wore, bought, and sold them. A partial list of famous diamonds in history follows.

• The Allnatt Diamond
• The Centenary Diamond
• The Cullinan Diamond, the largest rough gem-quality diamond ever found at 3106.75 carats
• The Deepdene
• The Dresden Green Diamond
• The Dudley Diamond
• The Eugenie Blue Diamond
• The Excelsior Diamond
• The Florentine Diamond
• The Golden Jubilee, the largest faceted diamond ever cut at 545.67 carats
• The Great Chrysanthemum Diamond
• The Heart of Eternity Diamond, perhaps the largest Fancy Vivid Blue
• The Hope Diamond, blue and supposedly cursed
• The Hortensia Diamond
• The Idol's Eye
• The Koh-i-Noor, very old (mentioned in Baburnama of 1526) and surrounded by legend
• The Millennium Star, the largest colorless (grade D), flawless diamond
• The Great Mogul Diamond
• The Moussaieff Red Diamond, the largest Fancy Vivid Red
• The Ocean Dream Diamond, the only known natural Fancy Deep Blue-Green
• The Oppenheimer Diamond
• The Orloff, an Indian rose cut rumored to have served as the eye of a Hindu statue
• The Portuguese Diamond
• The Premier Rose Diamond
• The Pumpkin Diamond, perhaps the largest Fancy Vivid Orange
• The Regent Diamond
• The Steinmetz Pink Diamond, the largest Fancy Vivid Pink
• The Taylor-Burton Diamond
• The Tiffany Yellow Diamond
• The Sancy
• The Star of the South
• The Vargas

The diamond supply chain is controlled by a limited number of powerful businesses, and is also highly concentrated in a small number of locations around the world. In fact, the amount of power which De Beers has consolidated historically prevented it from direct trade with the United States, as its trade practices led to an indictment for violating antitrust regulations (the case was settled in 2004). The concentration of power only loosens at the retail level, where diamonds are sold by a limited number of distributors, known as sightholders, to jewelers around the world.

Sources

Historically diamonds were known to be found only in alluvial deposits in southern India; India led the world in diamond production from the time of their discovery in approximately the 9th century BCE to the mid-18th century CE, but the commercial potential of these sources has been exhausted. The first non-Indian diamond source was found in Brazil in 1725. Today, most commercially viable diamond deposits are in Africa, notably in South Africa, Namibia, Botswana, the Rebuplic of the Congo,Angola and Sierra Leone. There are also commercial deposits being actively mined in the Northwest Territories of Canada, Siberia (mostly in yakutia territory, for example Mir pipe and Udachnaya pipe), Brazil, and in Northern and Western Australia. Diamond prospectors continue to search the globe for diamond-bearing kimberlite and lamproite pipes.
In some of the more politically unstable central African and west African countries, revolutionary groups have taken control of diamond mines, using proceeds from diamond sales to finance their operations. Diamonds sold through this process are known as conflict diamonds or blood diamonds. In response to public concerns that their diamond purchases were contributing to war and human rights abuses in central Africa and west Africa, the diamond industry and diamond-trading nations introduced the Kimberley Process in 2002, which is aimed at ensuring that conflict diamonds do not become intermixed with the diamonds not controlled by such rebel groups. The Kimberley Process provides documentation and certification of diamond exports from producing countries to ensure that the proceeds of sale are not being used to fund criminal or revolutionary activities. Although the Kimberly Process has been somewhat successful in limiting the number of conflict diamonds entering the market, conflict diamonds smuggled to market continue to persist to some degree.
Currently, gem production totals nearly 30 million carats (6,000 kg) of cut and polished stones annually, and over 100 million carats (20,000 kg) of diamonds are sold for industrial use each year. In 2003, this constituted total production of nearly US$9 billion in value.

Distribution

The Diamond Trading Company, or DTC, is a subsidiary of De Beers and markets rough diamonds produced both by De Beers mines and other mines from which it purchases rough diamond production; in whole, about two thirds of all rough diamonds pass through the company. DTC performs sophisticated sorting of rough diamonds into over 16,000 categories, and then sells bulk lots of rough diamonds to a limited number of sightholders a few times a year.
Once purchased by sightholders, diamonds are cut and polished in preparation for sale as gemstones. The cutting and polishing of rough diamonds is a specialized skill that is concentrated in a limited number of locations worldwide. Traditional diamond cutting centers are Antwerp, Amsterdam, Johannesburg, New York, and Tel Aviv. Recently, diamond cutting centers have been established in China, India, and Thailand. Cutting centers with lower costs of labor, notably Surat in Gujarat, India, handle a larger number of smaller carat diamonds, while smaller quantities of larger or more valuable diamonds are more likely to be handled in Europe or North America. Demonstrating this, India produces 90% of all cut and polished diamonds by number, but only 55% by value. The recent expansion of this industry in India, employing low cost labor, has allowed smaller diamonds to be prepared as gems than was previously economically feasible.
Diamonds which have been prepared as gemstones are sold on diamond exchanges called bourses. There are 24 registered diamond bourses. This is the final tightly controlled step in the diamond supply chain; wholesalers and even retailers are able to buy relatively small lots of diamonds at the bourses, after which they are prepared for final sale to the consumer. Diamonds can be sold already set in jewelry, or as is increasingly popular, sold unset ("loose"). According to the Rio Tinto Group, in 2002 the diamonds produced and released to the market were valued at US$9 billion as rough diamonds, US$14 billion after being cut and polished, US$28 billion in wholesale diamond jewelry, and retail sales of US$57 billion.

Diamond Color Grades Help you Choose a Diamond that Suits Your Budget

Four major components are considered when determining a diamond's quality and value. They are known as the Four C's: color, clarity, cut, and carat weight. Understanding these four diamond characteristics and how they interact can help you select a diamond that suits your tastes and your pocketbook.

Judging Diamond Color

Diamonds are not all truly colorless, but it's the colorless, often called white, which are diamonds that other shades are judged against.
The Gemological Institute of America (GIA) has devised a set of guidelines to grade diamond color. The color of graded diamonds is compared to the color of control stones, reselected gems of a specific color.

Diamond Color Grades

Colorless diamonds and diamonds that are yellow or yellowish brown are grouped into the categories shown below. These grades do not apply to fancy colored diamonds--they have their own color grading standards.
D-E-F
Colorless.
G-H-I-J
Nearly colorless.
K-L-M
Faintly tinted, usually yellow.
N-O-P-Q-R
Lightly tinted, usually yellow. Tint can be seen with the naked eye.
S-T-U-V-W-X-Y-Z
Tinted, usually yellow, may progress to brownish. Tint visible to the naked eye, even when mounted.

When nitrogen combines with the diamond crystals during the formation stage it causes a surplus electron in the bonding. This surplus electron absorbs blue light, thus giving off a yellow colour. Yellow diamonds also occur when aggregates of three nitrogens combine and cause surplus bond.

The elements of boron may also be substituted within a diamond during its formation. Boron absorbs red light, hence in the absence of nitrogen, diamonds containing boron are blue in colour. An example of a diamond containing boron is the famous Blue Hope diamond. Diamonds containing boron also exhibit unusual electrical properties and are semi-conductive in nature. Hydrogen is another impurity that, in high quantities, can cause grey or blue colouring in diamonds. However, these diamonds are not semi-conducting.

A vacancy in the regular lattice of atoms within a diamond results in a green colouring. Carbon atoms being knocked out of their regular position by other particles cause vacancies. The depth of colour usually extends about 2mm below the diamond's surface. At extremely high temperatures the vacancies can become mobile and can combine with nitrogen to form other colours such as mauve, orange, blue or gold.

It has been suggested that dislocations in the regular lattice of atoms, caused by severe forces deep in the earth, may be responsible for the brown colouring of champagne and cognac diamonds. The dislocated bonds may affect the light wavelength, thus producing a diamond which is coloured, but which contains no impurities.

It has also been suggested that combinations of dislocations, vacancies, and non-nitrogen impurities cause the much sought-after colouration in pink diamonds. However these theories are still being developed.